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1 ORGANIC CHEMISTRY MCQS

Vulcanized rubber belongs to which type of polymer?

  • Natural polymers
  • Semisynthetic polymers
  • Synthetic polymers
  • None of the above
Correct Answer: B. Semisynthetic polymers

Detailed Explanation

Polymers can be divided into three main classes: natural polymers, synthetic polymers, and semisynthetic polymers.




  • Natural polymers are obtained directly from nature, such as rubber, cellulose, and starch.




  • Synthetic polymers are fully man-made, such as nylon, PVC, and polyethylene.




  • Semisynthetic polymers are prepared by chemically modifying natural polymers to improve their properties.




Vulcanized rubber is a good example of a semisynthetic polymer. Natural rubber, which comes from the latex of rubber trees, is soft, sticky, and not very strong. When natural rubber is heated with sulfur, a process called vulcanization takes place.


In vulcanization, sulfur atoms create cross-links between the long chains of polyisoprene molecules present in natural rubber. These cross-links improve the physical and chemical properties of rubber. After vulcanization:




  • Rubber becomes stronger and tougher.




  • It shows better elasticity.




  • It resists heat, cold, and wear.




  • It becomes more durable for industrial uses.




This process was discovered by Charles Goodyear in 1839, and it completely changed the applications of rubber. Vulcanized rubber is now widely used in tires, conveyor belts, footwear, hoses, and industrial products.


The key point is that the base material (natural rubber) comes from nature, but after chemical treatment with sulfur, it no longer remains purely natural. At the same time, it is not completely man-made like synthetic rubbers. Therefore, it is correctly classified as a semisynthetic polymer.


In conclusion, vulcanized rubber is a semisynthetic polymer because it is formed by chemical modification of natural rubber through vulcanization.

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