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1 PHYSICAL CHEMISTRY MCQS

Which process occurs when no heat enters or leaves the system?

  • Isochoric
  • Isobaric
  • Adiabatic
  • Isothermal
Correct Answer: C. Adiabatic

Detailed Explanation

In thermodynamics, processes are classified based on how energy and work are exchanged with the surroundings. An adiabatic process occurs when no heat enters or leaves the system. In this process, the system is perfectly insulated, so all changes in energy occur only through work done by or on the system.


An isochoric process occurs at constant volume, where the system cannot do work by expansion, but heat can still be transferred. Isobaric processes occur at constant pressure, allowing heat to flow into or out of the system as the system expands or contracts. Isothermal processes occur at constant temperature, where heat transfer happens continuously to maintain temperature while the system does work.


Adiabatic processes are important in physics and chemistry because they describe rapid changes where there is no time for heat transfer. Examples include compression of gases in pistons, sound waves in air, and certain refrigeration cycles. The temperature of the system changes during an adiabatic process, even though heat is not exchanged.


In chemistry, understanding adiabatic processes is essential for thermodynamic calculations, enthalpy changes, and work-energy relationships. Adiabatic processes obey the first law of thermodynamics, where the change in internal energy equals the work done on or by the system.


By studying adiabatic processes, students learn how energy conservation works in isolated conditions where heat is not available for transfer. This knowledge helps in analyzing chemical reactions, gas behavior, and energy transformations in controlled systems.


The process in which no heat enters or leaves the system is the adiabatic process, making it a fundamental concept in Physical Chemistry.

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